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What is polycarboxylate ether PCE powder?

As the European Union tries to reduce its dependence on Russian energy, the Russian president recently said Russia would try to shift its energy exports to the east, adding that there was no way for European countries to give up Russian gas immediately.

Russia supplies about 40 percent of the EU's gas, and western sanctions imposed over the conflict with Ukraine have complicated financing and logistical arrangements for existing agreements, hitting Russian energy exports, the report noted.  

Russia has been building closer ties with China and other Asian countries as the European Union debates whether to impose sanctions on Russian gas and oil and member states seek supplies from elsewhere, Reuters said.  

"So-called partners from unfriendly countries admit that they cannot survive without Russian energy, including gas," the Russian president said in a televised government meeting. There is no reasonable alternative to Russian gas in Europe right now."  

He also said Europe was driving up energy prices and destabilizing markets by talking about cutting off Russia's energy supplies. Russia, which produces about a tenth of the world's oil and a fifth of its natural gas, will need new infrastructure to increase energy supplies to Asia, he said.

He ordered Moscow to submit a plan by June 1, including "the expansion of transport infrastructure to countries in Africa, Latin America, and the Asia-Pacific region".  

He also sought to clarify the possibility of integrating two pipelines -- the Sakhalin-Khabarovsk-Vladivostok gas pipeline in the Far East and the "Power of Siberia" gas pipeline to China -- into Russia's unified gas supply system. In theory, connecting these routes to larger gas networks could allow Russia to divert gas from Europe to Asia.

Because of the ever-changing international situation, the supply and prices of international bulk polycarboxylate ether,PCE powder are still very uncertain.

Chemical admixtures are in high demand in concrete technology to improve their properties such as durability, fluidity, setting and mechanical properties. Among these chemical admixtures,superplasticizers are mainly used to improve fluidity at relatively low water-cement ratios (W/C). First-generation superplasticizers (SP) such as sulfonated naphthalene formaldehyde condensate (SNF) and sulfamic acid formaldehyde condensate (ASF) can disperse cement particles through an electrostatic repulsion mechanism. A new generation of SP is based on polycarboxylate ether comb copolymers with carboxyl groups and poly(ethylene oxide) (PEO) side chains. PCE copolymers can generate electrostatic repulsion and steric hindrance, therefore, they provide better performance than the older generation. The molecular weight and side chain length of PCE can be easily tailored to make it superior to other kinds of SP.

 

Free radical polymerization (FRP) is widely used to prepare PCE copolymers, but has less control over molecular weight and molecular weight distribution (even with chain transfer agents to control the polydispersity index D = Mw/Mn values are usually higher than 1.5 molar mass) , producing polymer chains with broad molar mass distributions and potential variations in chemical composition Monomers with different reactivity. Over the past two decades, the controlled radical polymerization technique has been developed as a general method that provides free radical synthesis of polymers with predetermined molecular weights and narrow molar mass dispersion. Reversible addition-fragmentation chain transfer (RAFT) polymerization is a controlled/living radical polymerization technique that is compatible with a wide variety of monomers. Only very few studies have used RAFT polymerization to prepare PCE superplasticizers, focusing on block copolymers ignoring their potential applications in PCE random copolymers.

 

To gain an accurate understanding of the effects of side chain length and charge properties on PCE adsorption behavior, we employed RAFT polymerization in this work to obtain well-defined copolymers with different side chains and functions, enabling a more systematic assessment of the structural parameters of PCE. Performance. This is the first study to report the use of well-defined copolymers (D < 1.3) to compare the effects of side chain length and charge type of PCE on the dispersibility of cement pastes. In this study, two copolymers containing COO - or SO 3 - as charge types (PCE and PSE, respectively) were synthesized to investigate the effect of specific functional negatively charged groups on the adsorption and rheological properties of cement pastes. influences. On the other hand, in the case of PCE copolymers, three different PEO side chain lengths were employed to study their effect on cement fluidity. Adsorption studies, zeta potential measurements, mobility and rheological properties are also explored in this work.



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The COVID-19 pandemic has affected economies and chemical companies in many countries around the world. Measures such as extending holidays and resuming work were taken to control the development of the epidemic, and the normal operation of some chemical enterprises was also affected to some extent.

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